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VPRS condition type captures COst of the material. This Value for Condition type VPRS is copied from Valuation segment from Material master .i.e .Depending on customisation of Condition type – condition  Category.

Moreover the item category of the sales order Determine cost should be marked in VOV7

Item category : Determine cost checkbox is checked by this condition type before calculating the material cost.

 

Reference:

http://scn.sap.com/thread/1381743